Monday, August 24, 2009

Arc furnace

An electric arc furnace (EAF) is a furnace that heats charged material by means of an electric arc.
Arc furnaces range in size from small units of approximately one ton capacity (used in foundries for producing cast iron products) up to about 400 ton units used for secondary steelmaking. Arc furnaces used in research laboratories and by dentists may have a capacity of only a few dozen grams. Electric arc furnace temperatures can be up to 1,800 degrees Celsius. Arc furnaces differ from induction furnaces in that the charge material is directly exposed to the electric arc, and the current in the furnace terminals passes through the charged material.
History:-
In the 19th century, a number of men had employed an electric arc to melt iron. Sir Humphry Davy conducted an experimental demonstration in 1810; welding was investigated by Pepys in 1815; Pinchon attempted to create an electrothermic furnace in 1853; and, in 1878 - 79, Sir William Siemens took out patents for electric furnaces of the arc type.
The first electric arc furnaces were developed by Paul Héroult, of France, with a commercial plant established in the United States in 1907. Initially "electric steel" was a specialty product for such uses as machine tools and spring steel. Arc furnaces were also used to prepare calcium carbide for use in carbide lamps. The Stessano electric furnace is an arc type furnace that usually rotates to mix the bath. The Girod furnace is similar to the Héroult furnace.
While EAFs were widely used in World War II for production of alloy steels, it was only later that electric steelmaking began to expand. The low capital cost for a mini-mill - around US$140-200 per ton of annual installed capacity, compared with US$1,000 per ton of annual installed capacity for an integrated steel mill - allowed mills to be quickly established in war-ravaged Europe, and also allowed them to successfully compete with the big United States steelmakers, such as Bethlehem Steel and U.S. Steel, for low-cost, carbon steel 'long products' (structural steel, rod and bar, wire and fasteners) in the U.S. market.
When Nucor - now one of the largest steel producers in the U.S.[1] - decided to enter the long products market in 1969, they chose to start up a mini-mill, with an EAF as its steelmaking furnace, soon followed by other manufacturers. Whilst Nucor expanded rapidly in the Eastern US, the companies that followed them into mini-mill operations concentrated on local markets for long products, where the use of an EAF allowed the plants to vary production according to local demand. This pattern was also followed globally, with EAF steel production primarily used for long products, while integrated mills, using blast furnaces and basic oxygen furnaces, cornered the markets for 'flat products' - sheet steel and heavier steel plate. In 1987, Nucor made the decision to expand into the flat products market, still using the EAF production method[2].
Construction:-
An electric arc furnace used for steelmaking consists of a refractory-lined vessel, usually water-cooled in larger sizes, covered with a retractable roof, and through which one or more graphite electrodes enter the furnace. The furnace is primarily split into three sections:
the shell, which consists of the sidewalls and lower steel 'bowl'; the hearth, which consists of the refractory that lines the lower bowl; the roof, which may be refractory-lined or water-cooled, and can be shaped as a section of a sphere, or as a frustum (conical section). The roof also supports the refractory delta in its centre, through which one or more graphite electrodes enter. The hearth may be hemispherical in shape, or in an eccentric bottom tapping furnace (see below), the hearth has the shape of a halved egg. In modern meltshops, the furnace is often raised off the ground floor, so that ladles and slag pots can easily be maneuvered under either end of the furnace. Separate from the furnace structure is the electrode support and electrical system, and the tilting platform on which the furnace rests. Two configurations are possible: the electrode supports and the roof tilt with the furnace, or are fixed to the raised platform.
A typical alternating current furnace has three electrodes. Electrodes are round in section, and typically in segments with threaded couplings, so that as the electrodes wear, new segments can be added. The arc forms between the charged material and the electrode, the charge is heated both by current passing through the charge and by the radiant energy evolved by the arc. The electrodes are automatically raised and lowered by a positioning system, which may use either electric winch hoists or hydraulic cylinders. The regulating system maintains approximately constant current and power input during the melting of the charge, even though scrap may move under the electrodes as it melts. The mast arms holding the electrodes carry heavy busbars, which may be hollow water-cooled copper pipes carrying current to the electrode holders. Modern systems use 'hot arms', where the whole arm carries the current, increasing efficiency. These can be made from copper-clad steel or aluminium. Since the electrodes move up and down automatically for regulation of the arc, and are raised to allow removal of the furnace roof, heavy water-cooled cables connect the bus tubes/arms with the transformer located adjacent to the furnace. To protect the transformer from heat, it is installed in a vault.
The furnace is built on a tilting platform so that the liquid steel can be poured into another vessel for transport. The operation of tilting the furnace to pour molten steel is called "tapping". Originally, all steelmaking furnaces had a tapping spout closed with refractory that washed out when the furnace was tilted, but often modern furnaces have an eccentric bottom tap-hole (EBT) to reduce inclusion of nitrogen and slag in the liquid steel. These furnaces have a taphole that passes vertically through the hearth and shell, and is set off-centre in the narrow 'nose' of the egg-shaped hearth. It is filled with refractory sand, such as olivine, when it is closed off. Modern plants may have two shells with a single set of electrodes that can be transferred between the two; one shell preheats scrap while the other shell is utilised for meltdown. Other DC-based furnaces have a similar arrangement, but have electrodes for each shell and one set of electronics.
AC furnaces usually exhibit a pattern of hot and cold-spots around the hearth perimeter, with the cold-spots located between the electrodes. Modern furnaces mount oxygen-fuel burners in the sidewall and use them to provide chemical energy to the cold-spots, making the heating of the steel more uniform. Additional chemical energy is provided by injecting oxygen and carbon into the furnace, historically this was done through lances in the slag door, noways this is mainly done through multiple wall-mounted injection units.
A mid-sized modern steelmaking furnace would have a transformer rated about 60,000,000 volt-amperes (60 MVA), with a secondary voltage between 400 and 900 volts and a secondary current in excess of 44,000 amperes. In a modern shop such a furnace would be expected to produce a quantity of 80 metric tonnes of liquid steel in approximately 60 minutes from charging with cold scrap to tapping the furnace. In comparison, basic oxygen furnaces can have a capacity of 150-300 tonnes per batch, or 'heat', and can produce a heat in 30-40 minutes. Enormous variations exist in furnace design details and operation, depending on the end product and local conditions, as well as ongoing research to improve furnace efficiency - the largest scrap-only furnace (in terms of tapping weight and transformer rating) is in Turkey, with a tap weight of 300 metric tonnes and a transformer of 300 MVA.
To produce a ton of steel in an electric arc furnace requires approximately 400 kilowatt-hours per short ton of electricity, or about 440kWh per metric tonne; the theoretical minimum amount of energy required to melt a tonne of scrap steel is 300kWh (melting point 1520°C/2768°F). Therefore, the 300-tonne, 300 MVA EAF mentioned above will require approximately 132 MWh of energy to melt the steel, and a 'power-on time' (the time that steel is being melted with an arc) of approximately 37 minutes, allowing for the power factor. Electric arc steelmaking is only economical where there is plentiful electricity, with a well-developed electrical grid.
Operation:-
Scrap metal is delivered to a scrap bay, located next to the melt shop. Scrap generally comes in two main grades: shred (whitegoods, cars and other objects made of similar light-gauge steel) and heavy melt (large slabs and beams), along with some direct reduced iron (DRI) or pig iron for chemical balance. Some furnaces melt almost 100% DRI. The scrap is loaded into large buckets called baskets, with 'clamshell' doors for a base. Care is taken to layer the scrap in the basket to ensure good furnace operation; heavy melt is placed on top of a light layer of protective shred, on top of which is placed more shred. These layers should be present in the furnace after charging. After loading, the basket may pass to a scrap pre-heater, which uses hot furnace off-gases to heat the scrap and recover energy, increasing plant efficiency. The scrap basket is then taken to the melt shop, the roof is swung off the furnace, and the furnace is charged with scrap from the basket. Charging is one of the more dangerous operations for the EAF operators. There is a lot of energy generated by multiple tonnes of falling metal; any liquid metal in the furnace is often displaced upwards and outwards by the solid scrap, and the grease and dust on the scrap is ignited if the furnace is hot, resulting in a fireball erupting. In some twin-shell furnaces, the scrap is charged into the second shell while the first is being melted down, and pre-heated with off-gas from the active shell. Other operations are continuous charging - pre-heating scrap on a conveyor belt, which then discharges the scrap into the furnace proper, or charging the scrap from a shaft set above the furnace, with off-gases directed through the shaft. Other furnaces can be charged with hot (molten) metal from other operations. After charging, the roof is swung back over the furnace and meltdown commences. The electrodes are lowered onto the scrap, an arc is struck and the electrodes are then set to bore into the layer of shred at the top of the furnace. Lower voltages are selected for this first part of the operation to protect the roof and walls from excessive heat and damage from the arcs. Once the electrodes have reached the heavy melt at the base of the furnace and the arcs are shielded by the scrap, the voltage can be increased and the electrodes raised slightly, lengthening the arcs and increasing power to the melt. This enables a molten pool to form more rapidly, reducing tap-to-tap times. Oxygen is also lanced into the scrap, combusting or cutting the steel, and extra chemical heat is provided by wall-mounted oxygen-fuel burners. Both processes accelerate scrap meltdown. An important part of steelmaking is the formation of slag, which floats on the surface of the molten steel. Slag usually consists of metal oxides, and acts as a destination for oxidised impurities, as a thermal blanket (stopping excessive heat loss) and helping to reduce erosion of the refractory lining. For a furnace with basic refractories, which includes most carbon steel-producing furnaces, the usual slag formers are calcium oxide (CaO, in the form of burnt lime) and magnesium oxide (MgO, in the form of dolomite and magnesite). These slag formers are either charged with the scrap, or blown into the furnace during meltdown. Another major component of EAF slag is iron oxide from steel combusting with the injected oxygen. Later in the heat, carbon (in the form of coke or coal) is lanced into this slag layer, reacting with the iron oxide to form metallic iron and carbon monoxide gas, which then causes the slag to foam, allowing greater thermal efficiency, and better arc stability and electrical efficiency. The slag blanket also covers the arcs, preventing damage to the furnace roof and sidewalls from radiant heat. Once flat bath conditions are reached, i.e. the scrap has been completely melted down, another bucket of scrap can be charged into the furnace and melted down, although EAF development is moving towards single-charge designs. After the second charge is completely melted, refining operations take place to check and correct the steel chemistry and superheat the melt above its freezing temperature in preparation for tapping. More slag formers are introduced and more oxygen is lanced into the bath, burning out impurities such as silicon, sulfur, phosphorus, aluminium, manganese and calcium and removing their oxides to the slag. Removal of carbon takes place after these elements have burnt out first, as they have a greater affinity for oxygen. Metals that have a poorer affinity for oxygen than iron, such as nickel and copper, cannot be removed through oxidation and must be controlled through scrap chemistry alone, such as introducing the direct reduced iron and pig iron mentioned earlier. A foaming slag is maintained throughout, and often overflows the furnace to pour out of the slag door into the slag pit. Temperature sampling and chemical sampling (in the form of a 'chill' - a small, solidified sample of the steel) take place via automatic lances. Once the temperature and chemistry are correct, the steel is tapped out into a preheated ladle through tilting the furnace. As soon as slag is detected during tapping the furnace is rapidly tilted back towards the deslagging side, minimising slag carryover into the ladle. During tapping some alloy additions are introduced into the metal stream. Often, a few tonnes of liquid steel and slag is left in the furnace in order to form a 'hot heel', which helps preheat the next charge of scrap and accelerate its meltdown. During and after tapping, the furnace is 'turned around': the slag door is cleaned of solidified slag, repairs may take place, and electrodes are inspected for damage or lengthened through the addition of new segments; the taphole is filled with sand at the completion of tapping. For a 90-tonne, medium-power furnace, the whole process will usually take about 60-70 minutes from the tapping of one heat to the tapping of the next (the tap-to-tap time).

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